Using Two Different Approaches For The Creation Of Poly(3-Hexylthiophene)-Functionalized Siloxane Nanoparticles For Organic-Based Solar Cells
Poly(3-hexylthiophene)-functionalized silsesquioxane nanoparticles were prepared from direct hydrolysis and condensation of P3HT-silane precursor using âgrafting fromâ and âgrafting toâ methods. The size, shape, and surface morphology of these polymer grafts particles were visualized using transmission electron microscopy and scanning electron microscopy. Their compositions confirmed by FTIR, thermogravimetric analysis and elemental analysis. The XRD analysis revealed the polymer orientation and packing pattern of the nanocomposites, indicating the highly ordered lamella stacks of P3HT polymer chains. The photovoltaic performance of the blends of P3HT-nanohybrid with the C60 derivative PCBM was evaluated upon annealation in different temperatures, ranging from 50°C to 150 °C. The power conversion efficiency of the best test device was 2.46% (3.8%) for the device configuration of ITO/PEDOT:PSS/P3HT-NPs:PCBM/LiF/Al.
Wright, Nicholas A., "Using Two Different Approaches for the Creation of Poly(3-Hexylthiophene)-Functionalized Siloxane Nanoparticles for Organic-Based Solar Cells" (2012). Honors College Capstone Experience/Thesis Projects. Paper 372. https://digitalcommons.wku.edu/stu_hon_theses/372
Nicholas Wright, Amar Patel, Jenna Binion, and Hemali Rathnayake. âPoly(3-hexylthiophene)-functionalized Siloxane Nanoparticles for Organic-based Solar Cells.â Polymeric Materials Science & Engineering 2012, 106, 431. http://www.gbv.de/dms/tib-ub-hannover/720437180.pdf